Bronkhorst
Application note

燃燒分析中的流量控制

準確且可重複的流量控制

一家元素分析設備的 OEM 製造商要求 Bronkhorst 提供一種解決方案,用於控制向燃燒爐和燃燒分析中的檢測部分供應氣體。 運載氣體的準確且可重現的氣流在這裡對於燃燒至關重要。 

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什麼是燃燒分析?
在元素分析領域,燃燒分析是一種測量樣品中碳、氫、氮、硫和氧等元素總含量的技術。 它可用於闡明塑料的行為、確定(生物)燃料的質量、確定土壤中的氮含量或驗證食品質量。 在燃燒分析中,樣品與氧氣一起燃燒,燃燒氣體被掃到檢測器以確定這些氣體和元素的總量。

Flow control in Combustion analysis for soil sample

燃燒分析應用要求

為了實現受控燃燒,需要準確地配給作為反應化合物的氧氣。 準確且可重現的氦氣流量對於將燃燒產物送至檢測器的載氣是必要的。 此外,需要流量控制器能夠處理少量樣品,並且它們本身很小以減少分析實驗室中的設備佔地面積。

有關痕量元素分析的更多信息

重要話題

  • 元素分析的準確性和可重複性
  • 流量裝置佔地面積小
  • 低成本


Process solution for flow control

The Bronkhorst solution consists of three mass flow controllers of the EL-FLOW Base series, that are controlled by a PLC inside the analysis equipment. A sample is accurately weighted and fed into the combustion oven of the analyser. One of the mass flow controllers is used to supply oxygen as a reactant in the combustion process. Oxygen needs to be dosed accurately to save catalyst, and the flow through the combustion oven needs to be constant

In the combustion oven, the elements carbon, hydrogen, nitrogen and sulphur are combusted to their respective oxidised forms CO2, H2O, NO2 and SO2

Flow scheme Hydrogen storage in metal hydride
Flow scheme

The second mass flow controller introduces a helium flow into the combustion oven, which serves a as carrier gas for these combustion gases. Water (H2O) is removed in a water trap downstream of the combustion oven, and the helium flow transports the combustion gases through a gas chromatographical (GC) column which separates these constituents from each other. Then the gases are conveyed to a thermal conductivity detector (TCD) to quantitatively determine the amount of each of these gases, and in turn of the corresponding elements. The third mass flow controller supplies a helium gas flow to the thermal conductivity detector.

For the analysis of oxygen in a sample, the analyser needs to be operated in a reducing mode without supplying gaseous oxygen. Helium is still used here as sweep gas. The oxygen is converted into a compound that is separated in the chromatographical (GC) column to be detected by the thermal conductivity detector.

To be able to accurately determine the composition of very small samples, the Bronkhorst devices, EL-FLOW Base and MANI-FLOW solutions, can accurately and reproducibly control small gas flows in the range of 100 ml/min. Moreover, the compactness of the gas flow devices themselves makes them a very useful part of the analysis equipment to reduce the footprint in the lab, savings costs.  

Prior to using flow controllers, the analysis equipment applied a pressure difference as a driving force for the combustion gases to be transported through the process. Indeed, the combustion analysis process is more accurate by using flow devices.

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